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OUR PRODUCTS:

 

 

Organometallic complexes

 

Nanomaterials

 

  • Organometallic complexes:

 

Contact us if you want to use a complex not mentionned in the list hereunder.


In order to answer as well as possible your needs, we continuously develop various organometallic complexes.
We undertake to make our offer progress according to the demands we receive.

 

All our produtcs are purified and tested. We keep the results of these analysis available.
Air sensitive products are packaged under argon, in sealed vials.

We advice to keep your products under the exclusion of moisture, in cooled place for optimum time of storage.

SILVER

[Ag (iPr-Me-AMD)]x (x=2,3): (N,N'-diisopropylacetamidinato) Silver (I)

 

Physical appearance: white microcrystals
Molecular weight: 249,11 g .mol-1 (monomer)
Advices: air and heat sensitive – keep under argon, store cold.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)


Reference: 1AG001
ARSENIC

As(SiMe3)3: tris(trimethylsilyl) Arsine

Physical appearance: colorless liquid
Molecular weight: 294,49 g .mol-1
Advices: air and heat sensitive – keep under argon, store at -20°C.

Precursor for III-V semiconductor materials

Reference: 1AS001

COBALT

Co(h3-C8H13)(h4-C8H12): (1,5-cyclooctadiene)(cyclooctadienyl) Cobalt (I)

Physical appearance: black crystals
Molecular weight: 276,31 g .mol-1
Advices: air and heat sensitive – keep under argon, store at -20°C.

Catalyst for cyclisation of alkynes and nitriles.

Reference: 1CO001

{Co[N(SiMe3)2]2}2: bis(bistrimethylsilylamido) Cobalt (II)

Physical appearance: green crystals
Molecular weight: 759,41 g .mol-1
Advices: air sensitive – keep under argon.

Catalyst for polymerisation of b-lactame

Reference: 1CO002

Co (iPr-Me-AMD)2: bis(N,N'-diisopropylacetamidinato) Cobalt (II)

Physical appearance: dark green crystals
 Molecular weight: 341,41 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1CO003

Co (iPr-nBu-AMD)2: bis(N,N'-diisopropyl-2-nbutylamidinato) Cobalt (II)

Physical appearance: blue-green powder
Molecular weight: 425,57 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1CO004

Co (Cy-Me-AMD)2: bis(N,N'-dicyclohexylacetamidinato) Cobalt (II)

Physical appearance: dark green crystals
Molecular weight: 501,66 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1CO005
COPPER

[Cu(iPr-Me-AMD)]2: (N,N'-diisopropylacetamidinato) Copper (I)

Physical appearance: white microcrystals
Molecular weight: 409,56 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1CU001

[Cu(iPr-nBu-AMD)]2: (N,N'-diisopropyl-2-nbutylamidinato) Copper (I)

Physical appearance: white microcrystals
Molecular weight: 493,73 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1CU002

TIN

[Sn(NMe2)2]2: bis(dimethylamido) Tin (II)

Physical appearance: cream colored crystals
Molecular weight: 413,73 g .mol-1
Advices: air, light and heat sensitive – keep under argon, under the exclusion of light, store at
-20°C

Precursor for Chemical Vapor Deposition (CVD)

Reference: 1SN001

Sn(iPr-Me-AMD)2: bis(N,N'-diisopropylacetamidinato) Tin (II)

Physical appearance: yellow crystals
Molecular weight: 401,18 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1SN002

IRON

{Fe[N(SiMe3)2]2}2: bis(bistrimethylsilylamido) Iron (II)

Physical appearance: yellow-green liquid
Molecular weight: 753,24 g .mol-1
Advices: air sensitive – keep under argon.

Catalyst for polymerisation of b-lactame

Reference: 1FE001

[Fe(iPr-Me-AMD)2]2: bis(N,N'-diisopropylacetamidinato) Iron (II)

Physical appearance: olive-green microcrystals
Molecular weight: 676,64 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1FE002

Fe(C9H7)2: bis(indenyl) Iron (II)

Physical appearance: black crystals
Molecular weight: 286,15 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for nanomaterials

Reference: 1FE003

Fe(tBu-Me-AMD)2: bis (N,N'-ditertiobutylacetamidinato) Iron (II)

Physical appearance: white crystals
Molecular weight: 394,42 g .mol-1
Advices: air and heat sensitive – keep under argon, store at -20°C.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1FE004

MANGANESE

[Mn(iPr-Me-AMD)2]2: bis(N,N'-diisopropylacetamidinato) Manganese (II)

Physical appearance: light yellow microcrystals
Molecular weight: 674,82 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1MN001

NICKEL

Ni(iPr-Me-AMD)2: bis(N,N'-diisopropylacetamidinato) Nickel (II)

Physical appearance: brown crystals
Molecular weight: 341,17 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1NI001

PALLADIUM

Pd(C7H8)(C4H2O3): (2,5-norbornadiene)(anhydride maleique) Palladium (0)

Physical appearance: cream solid
Molecular weight: 296,62 g .mol-1
Advices: air and heat sensitive - keep under argon, store at -20°C.

 

Reference: 1PD001

Pd2(dba)3: tris(dibenzylideneacetone) dipalladium (0)

Physical appearance: purple needles
 Molecular weight: 915,74 g .mol-1
Advices: air stable.

Catalyst for carbon-nitrogen bonds forming and for a-arylation of ketones

Reference: 1PD002

PdCl2(h4-C8H12): (1,5-cyclooctadiene) dichloropalladium (II)

Physical appearance: yellow powder
Molecular weight: 285,5 g .mol-1
Advices: air stable.

 

Reference: 1PD003

PdCl2(C6H5-CN)2: trans-bisbenzonitriledichloropalladium (II)

Physical appearance: yellow powder
Molecular weight: 383,6 g .mol-1
Advices: air sensitive – keep under argon (possible exposure to air for a short time).

Catalyst for diamination of conjugated dienes

Reference: 1PD004

PLATINUM

Pt(CH3)2(h4-C8H12): (1,5-cyclooctadiene) dimethylplatinum (II)

Physical appearance: cream white crystals
Molecular weight: 333,33 g .mol-1
Advices: air stable.

Precursor for Chemical Vapor Deposition (CVD)

Reference: 1PT001

PtCl2(h4-C8H12): (1,5-cyclooctadiene) dichloroplatinum (II)

Physical appearance: white powder
Molecular weight: 374,2 g .mol-1
Advices: air stable.


Reference: 1PT002

Pt(h4-C8H12)2: bis(1,5-cyclooctadiene) Platinum (0)

Physical appearance: white crystals
Molecular weight: 411,45 g .mol-1
Advices: air stable.

 

Reference: 1PT003

PtCl2(C6H5-CN)2: trans-bisbenzonitriledichloroplatinum (II)

Physical appearance: yellow microcrystals
Molecular weight: 472,23 g .mol-1
Advices: air stable.



Reference: 1PT004

Pt(C7H10)3: tris(norbornene) Platinum (0)

Physical appearance: white crystals
Molecular weight: 477,55 g .mol-1
Advices: air stable - store with a norbornene crystal to prevent from decomposition

Catalyst for hydrosilylation

Reference: 1PT005

RUTHENIUM

Ru(h4-C8H12)(h6-C8H10): (1,5-cyclooctadiene)(1,3,5-cyclooctatriene) Ruthenium (0)

Physical appearance: orange crystals
Molecular weight: 315,42 g .mol-1
Advices: air sensitive – keep under argon.

Selective catalyst for alkylation of amines

Reference: 1RU001

TANTALUM

Ta(CHtBu)(CH2tBu)3: tris(neopentyl)(neopentylidene) Tantalum (V)

Physical appearance: orange-red microcrystals
Molecular weight: 464,51 g .mol-1
Advices: air sensitive – keep under argon.

Catalyst for metathesis of olefins

Reference: 1TA001

VANADIUM

V(iPr-Me-AMD)3: tris(N,N'-diisopropylacetamidinato) Vanadium (III)

Physical appearance: brown-red crystals
Molecular weight: 474,65 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1V001

ZINC

Zn(Cy)2: dicyclohexyl Zinc (II)

Physical appearance: white crystals
Molecular weight: 231,70 g .mol-1
Advices: air, light and heat sensitive – keep under argon, under the exclusion of light,store at
-20°C

Precursor for Chemical Vapor Deposition (CVD) CVD

Reference: 1ZN001

Zn(iPr-Me-AMD)2: bis(N,N'-diisopropylacetamidinato) Zinc (II)

Physical appearance: white microcrystals
Molecular weight: 347,86 g .mol-1
Advices: air sensitive – keep under argon.

Precursor for Atomic Layer Deposition (ALD) – Chemical Vapor Deposition (CVD)

Reference: 1ZN002

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  • Nanomaterials:

Thanks to organometallic chemistry methods, we synthesize nanoparticles with controlled size and shape.
The choice of these morphologic factors gives new properties to the materials.
Presented in powders or in solutions, they could be integrated in many applications.

    • Metallic nanoparticles and metal oxides nanoparticles:

The methods we use allow the forming of non-oxidized nanoparticles of different metals (iron, cobalt...) and it is possible to add oxidizing agents to obtain oxides nanoparticles.

    • Morphology of the particles:

We can obtain materials containing particles with homogeneous shape and monodispersed size.
> Size: from 3 nm
> Shapes: spheres, cubes, rods, wires...

    • Nanomaterials in powders and solutions:

Our nanomaterials could be dispersed in many matrixes and conditioned under inert atmosphere:
> in solution: aqueous or organic
> in powder: pures or dispersed in polymers for example.

    • Their properties:

In function of the selected combination of size/shape/metal, the materials display characteristics such as:
> magnetic properties
> optical properties
> catalytic properties
> electrical properties
> semi-conducting properties

    • Few applications:

The modularity of these materials allow their integration in various fields of activity such as microelectronic (data storage), life science (detection and treatment), energy, automotive, aeronautic...

We propose to study your project of nanomaterial integration in your applications, in function of your needs.

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